More sustainable epoxy thanks to phosphorus

(empa.ch)

46 points | by JeanKage 4 days ago

6 comments

  • rectang 2 hours ago
    OT: It's difficult for me with my imperfect vision to read this web page because of inadequate contrast between body-text and background. Firefox dev tools measures a 3.52 contrast ratio — WCAG guidelines recommend 7:1 (AAA rating) or 4.5:1 (AA rating). However, viewing the page in reader mode seems to work as a solution.
  • rectang 2 hours ago
    There are two recycling mechanisms:

    > After use, the material can simply be ground into powder and pressed into a new shape while heated, causing the bonds to rearrange themselves. This is known as thermomechanical recycling.

    > it can also be chemically dissolved

    I wonder whether either of these opens up any practical durability issues for this variety of epoxy.

    • vesinisa 30 minutes ago
      This is covered in the article.

      > We have carried out ten [thermomechanical] recycling cycles, and the epoxy has not lost any significant mechanical strength in the process

      Chemical dissolving is only needed for carbon fiber composite. 90% of the resin was cited to be recoverable in this process.

      • rectang 22 minutes ago
        I saw that passage, which addresses that durability doesn't degrade through recycling cycles. But what I was curious about was whether this epoxy is more susceptible to weakening when exposed to heat in working environments, perhaps at lower threshold temperatures than common epoxy. Similarly, I wondered whether there were any chemicals which are commonly encountered in working environments which could serve as dissolving agents and damage this epoxy.
    • hammock 38 minutes ago
      I don’t know of any recycled polymer that doesn’t have at least somewhat compromised durability. Doesn’t mean it’s useless though
  • zahlman 1 hour ago
    It appears we got a relevant XKCD just in time: https://xkcd.com/3194/
  • pfdietz 4 hours ago
    This looks like recycling fetishism. It's perfectly fine to burn such materials, if they were obtained from non-fossil sources to start with, so there would be no net CO2 addition to the atmosphere.
    • westurner 3 hours ago
      An adjacent design validation question on a green chip factory and product design:

      Will Phytic acid in Lignin-Vitrimer encase burning CNT carbon nanotubes in a phosphorous char cage, this preventing health hazards and combustion?

      This says "phosphorous epoxy".

      FR4 silicon PCBs are N-doped and P-doped.

  • ComputerGuru 2 hours ago
    This is a presser (disguised as a science piece) from the company behind this; take it all with a grain of salt.

    Also, epoxy already contains harmful endocrine disruptors, adding forever chemicals like those found in almost all flame retardants is just adding fuel to the fire (pun not intended).

    • bootsmann 1 hour ago
      EMPA is not a company, it’s a Swiss government agency. Maybe you should apply the grain of salt to your own priors too…
      • ComputerGuru 1 hour ago
        Thanks for the correction but they're tooting their own horn either way.
    • s0rce 2 hours ago
      While this is just a press release its about the academic paper, which is open access https://www.sciencedirect.com/science/article/pii/S138589472...

      It doesnt seem like any of the authors are making this commercially currently

  • HardCodedBias 2 hours ago
    when I hear of industrial uses of phosphorus my ears prick up since phosphorus is a key limiting factor for life.

    A world where this actually became industrially very successful combined with a lack of recycling could potentially add large new sink for phosphorus.

    In general, be careful when creating a process which locks meaningful amount of phosphorus out of the biosphere.

    • s0rce 2 hours ago
      I can't imagine this approaches how much is used in agriculture for fertilizer.
    • pfdietz 2 hours ago
      When a general study was made back in the 1970s of the limits of substitutability and recyclability of mineral resources, it was found phosphorus likely dictates the minimum amount of mining needed in steady state. It occurs at an average concentration of about 0.1% in the continental crust.

      I worry just a bit about this in reference to LFP batteries.

    • Brian_K_White 2 hours ago
      I think that was a core plot point of a series of books by Niven I think. Humans are on a planet that has almost no phosphorus or maybe potassium in it's biosphere. Humans have to take it artificially by sprinkling a special salt on every meal. But it's very limited and expensive and so a significant part of the population are mentally handicapped to lesser or greater degrees, generation after generaion.

      Ah, Destiny's Road, and it was Potassium.

      "...dooming humanity to a slow mental extinction."

      Great.